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This is Geology Bites with 
Oliver Strimpel. 

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When the Earth formed, it was 
covered by a hot magma ocean. 

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At some point it cooled enough 
to form a solid surface thought 

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to be basaltic in composition, 
like today's oceanic crust. 

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Then at some point the surface 
began to differentiate into 

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different types of lithosphere, 
basaltic oceanic lithosphere, 

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and more silica rich continental
lithosphere. 

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How did this process occur? 
Were the first ancient 

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continents similar to the 
present day continents and did 

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the continents form in a burst 
of activity at a certain point 

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when differentiation occurred, 
or was it a gradual build up 

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over Earth history? 
Renee Tamblyn studies the early 

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Earth and in particular the role
of water in the formation of 

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continents. 
She's also exploring how the 

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production of hydrogen from 
geological processes could have 

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powered very early forms of 
life. 

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She's a postdoctoral researcher 
at the University of Bern. 

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Renee Tamblyn, welcome to 
Geology Bites. 

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Thank you very much, Oliver. 
It's an honour to be here. 

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Before we talk about how 
continents form, how confident 

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are we that the basic picture I 
laid out just now is correct, 

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namely that the Earth was born 
without any continents and that 

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these had to form at some later 
point in Earth history? 

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So although we don't have any 
rocks preserved from the 

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earliest part of the Earth, so 
particularly from about 4.56 

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billion years ago when the Earth
was first accreted, until about 

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4 billion years ago, which is 
the oldest rock we have, we 

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don't really have any picture of
what the Earth may have looked 

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like then because it's not 
preserved. 

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But I think we are quite 
confident that the Earth 

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certainly started as a magma 
ocean. 

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And we know that from this magma
ocean we could not make the 

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continents, as you mentioned, 
these silica rich continents. 

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They need much more complex 
geological processes to form 

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rather than just forming from a 
simple magma ocean. 

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So we know that at some point, 
and when is the big question, 

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these continents first emerged, 
that there must have been more 

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difficult, more complex 
geological processes at play 

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that allowed these continents to
differentiate. 

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And we know this because the 
chemical components which make 

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up the continental crust are 
very different from the oceanic 

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crust, or what would have been 
quite similar to this magma 

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ocean at the beginning. 
The continents today are quite 

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different from the continents in
the past. 

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The continents today are very 
rich in elements as such as 

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silica as you mentioned, but 
also potassium, whereas the 

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earliest continents, the ones 
from the Archaean, so this is 

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the time frame from 4 billion 
years ago to 2.5 billion years 

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ago, tend to be more rich in 
elements such as sodium and 

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calcium. 
So this leads us to think that 

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the processes we see today 
making our continents, our 

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potassium rich continents must 
have been quite different to the

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processes we saw in the 
Archaean. 

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Finally, the question of when 
the continental crust actually 

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formed is a huge question. 
And at Sciences, because as I 

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mentioned, we don't have a 
record from the 1st 500 million 

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years or so, but also it's a 
question between formation and 

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preservation. 
So we know we can form the 

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continents, but we also know 
they can be destroyed, they can 

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either be eroded or they can be 
buried back into the mantle and 

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lost to our geological record. 
So it's a balance between 

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creation and preservation. 
OK, so let's actually talk about

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how continents form. 
Do any of the first continents 

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survive to the present day to 
give us some clues as to how 

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they formed? 
So we do have evidence of some 

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very, very ancient continents on
the Earth, Luckily for us, and 

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as I mentioned, they're quite 
different to the younger 

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continents we see today. 
And this difference has spurred 

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a massive amount of research 
into these earliest continents. 

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We don't know if they were the 
first ones, but we certainly 

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hope they were some of the first
ones. 

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And these give us a lot of 
clues. 

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But it's kind of like you have 
an end product and you have to 

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go back and work out how it was 
formed, What were the 

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ingredients, what was the recipe
to make it. 

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And there's a few important 
things that we need to know. 

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We need to know the source rock 
because you can't create a rock 

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from nothing. 
There had to be some rock there 

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before that was affected to 
create the continent. 

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In this case probably melted or 
re melted. 

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And we also need to know what 
exact process did that, which is

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that process modified, it re 
melted it to make the continents

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that we see preserved now. 
And we think that either the 

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starting composition or the 
process, both or one of them at 

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least were different in the RTN 
to now. 

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Can we date the oldest 
continental cross fairly 

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confidently? 
Yes, we can. 

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So as I mentioned, the oldest 
rock we have is 4 billion years 

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old, but that's a small amount 
of rock. 

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But the first continents we can 
really find on Earth seem to be 

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around 3.8 billion years ago. 
And then we have them all 

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throughout the Archaeans. 
So we also have some nice ones 

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around 3.4 billion years ago, 
3.2 billion years ago. 

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So we seem to have a good 
picture of the continents 

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throughout the Archaean. 
What can we learn about the 

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processes that took place at the
beginning and formed the first 

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continents? 
Yes, If we go and look now, so 

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interestingly, these are key and
bits of rock. 

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They only cover about 8% of the 
continents we have now. 

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So we find these are cratons, 
they're all over the world 

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amazingly, but some of the 
oldest ones and the ones which 

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have had the most study, the 
most well preserved are in North

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America, the superior craton. 
We have very famous the couple 

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craton which is in South Africa.
And there's also several cratons

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in Australia, which are 
particularly old, many in India,

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Central Asia, China and also in 
South America. 

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And they are 80% dominated by 
one series of rocks, one 

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magmatic series of rocks. 
And we call these TTGS, which 

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stands for Tonalite Trundumite 
granodiarides. 

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Say that a bit more slowly for 
me. 

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Way too fast. 
Tonalite trundumite 

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granodiaride. 
So these tonalite, trundumite 

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granodiarides, they're magmatic 
rocks, they're igneous, they're 

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melted and they crystallize in 
the crust. 

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And these are these very high 
silica rocks, very high in 

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sodium, very high in calcium, 
and importantly, they're not 

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very dense, they're very 
buoyant. 

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This is what actually makes the 
continent, the fact that they're

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buoyant and thick and therefore 
are above the ocean. 

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So these TTGS, as we call them, 
we like to shorten it. 

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They seem to require sort of 
three things to form. 

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First of all, we need a starting
rock, as I said, something that 

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they had created from, and in 
this case we know it's a basalt.

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They come from the melting or 
remelting of basalts or mafic 

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rocks, as we also say. 
So these are rocks that are high

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in magnesium and iron. 
They also require temperature. 

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To melt a basalt, you need to 
take it to fairly high 

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temperatures, to more than 708 
hundred degrees Celsius, but 

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intriguingly, not that high 
temperature, so maybe less than 

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900°C. 
Prosteologist. 

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That's not too hot. 
And lastly, they seem to require

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water, which is an interesting 
thing, free water in these 

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rocks. 
These cratons are mostly TTGS, 

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but they're not entirely TTGS, 
are they? 

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No, they're not. 
Around 80% seem to be the other 

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20%, a series of rocks which we 
refer to as greenstone belts. 

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And greenstone comes from the 
fact that these rocks tend to be

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green, very inventive, but 
they're actually super 

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interesting. 
They're very diverse, unlike our

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TTGS, and they seem to be 
primarily made of volcanic 

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rocks, so rocks which erupted. 
And these, unlike the TTGS, are 

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not so rich in silica. 
They're actually very, very 

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mafic. 
So they have high amounts of 

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magnesium and iron. 
And the rest of these TTGS, 

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where it's not volcanic, tend to
be sedimentary. 

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So we have a lot of sedimentary 
rocks also preserved in these 

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greenstone belts. 
So mostly these TTGS, but a 

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certain number of these high 
magnesium volcanic rocks, those 

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are referred to as chromatiates,
aren't they? 

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Yes, true, including 
cholateates. 

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That's my current area of work 
for the past four years is 

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looking at these rocks called 
Commadiites, which is a great 

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name named after a place called 
the Kamati River in South 

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Africa. 
And these are really strange 

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rocks because they are lavas and
they're incredibly magnesium, so

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20 plus weight percent 
magnesium, which is a lot. 

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And interestingly, they seem to 
have erupted at extremely high 

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temperatures, so maybe 1600°C, 
which is incredibly toasty. 

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And these incredibly high 
temperatures seem to come from 

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the fact that commodities were 
generated very deep in the 

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mantle, actually probably very 
close to the mantle core 

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boundary. 
And they then ascend through the

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mantle as a mantle plume and 
erupt in the arcane to form 

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these commodities. 
And we don't find them really 

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post Archaean. 
There are some very rare 

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examples, but most of them in 
the Archaean. 

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So it seems to be something very
special to the Archaean. 

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And that is because, simply, the
Earth was a lot hotter back 

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then. 
Does the disappearance of 

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Comatia and TT GS I guess does 
that happen at a particular time

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in Earth history then? 
Yes, absolutely. 

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So it's very intriguing that the
TTGS, they seem to die out after

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the Ikeans. 
So from 2 billion years is some 

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of the last big swaths of them, 
the Commadiites become 

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incredibly rare after 2.5 
billion years. 

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So they seem to have really 
dominated the geological record 

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in the Ikean and then they 
suddenly start to really die out

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and become less well preserved 
in the geological record. 

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And do we have a theory as to 
why that is? 

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For the commodities, the idea 
seems to be that the earth 

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cooled beyond some kind of 
tipping point. 

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So the earth at the beginning 
was very warm thanks to its 

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accretion, the kinetic force of 
accretion, and also from the 

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decay of radioactive elements 
which slowly died out over time.

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So it seems around 2.5 to 2 
billion years some sort of 

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switch went off. 
Suddenly the Earth cooled to 

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some point where we weren't 
making these commodities, these 

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ultra hot mantle plumes as much 
anymore. 

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Intriguingly, this also 
corresponds to some very 

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significant atmospheric events, 
but maybe we can touch on that 

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later. 
So I'm trying to form a picture 

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then. 
So we have these TTGS which were

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platonic rocks. 
They're part of that ranatoid 

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family on the one hand. 
And then you have the volcanic 

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rocks that I guess spewed out 
over them, the high magnesium 

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comatiites, and then sedimentary
rocks as well, which I guess are

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secondary processes. 
And then after the end of the 

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Archaean, some new or slightly 
altered processes took place to 

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continue to build the 
continents. 

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Is that right? 
I think that's a very good way 

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of phrasing it. 
Some people might say that that 

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could be actually the emergence 
of plate tectonics. 

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And when I say plate tectonics, 
I mean modern plate tectonics. 

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So where we have very stiff 
rigid plates and very deep and 

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very steep subductions when the 
oceanic plate is thrust under 

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the continental plate and a lot 
of pupils align that with the 

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end of the reign of TTGS and 
commodities. 

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I personally think the picture 
is a little bit more 

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complicated. 
I think we have local examples 

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of subduction and some sort of 
horizontal tectonics, probably 

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in the Archaean, but there does 
some seem to be some major 

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change. 
As I mentioned, you're 

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especially interested in the 
role of water in the process of 

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forming continental crust. 
Can you tell us about that? 

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Yes. 
So water is a vital ingredient 

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in the continental crust, 
whether it be in the ancient 

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earth, in the Archaean or in the
modern earth. 

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And the key thing is how do we 
get the water to high 

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temperatures? 
Because what we really need is 

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water to lower the solidus of 
rocks like basalts, IE make 

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melting of these rocks or re 
melting of these rocks easier 

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because that's how we form 
either our TTGS in the Archaean 

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or our granites in the modern 
Earth. 

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There's been a lot of research 
looking into the sorts of rocks 

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that might be able to carry this
water capture in the crystal 

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structure and also carry this 
water to higher temperatures. 

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00:13:08,080 --> 00:13:10,840
And by high temperatures I mean 
more than 700°. 

228
00:13:10,840 --> 00:13:16,040
So the temperatures of melting 
of these vessels in the modern 

229
00:13:16,040 --> 00:13:18,080
Earth. 
We understand this very well in 

230
00:13:18,080 --> 00:13:22,280
subduction zones where we have 
oceanic crust which is being 

231
00:13:22,280 --> 00:13:26,200
pushed down into the mantle, but
in the Ikean this is a bit more 

232
00:13:26,200 --> 00:13:30,080
of an unknown. 
You mentioned the solidus, so 

233
00:13:30,920 --> 00:13:36,040
when rocks are wet, the solidus 
is lower, which means they melt 

234
00:13:36,040 --> 00:13:37,760
at much lower temperatures. 
Is that right? 

235
00:13:38,200 --> 00:13:42,400
Precisely, yes, and also they 
tend to melt in larger volumes. 

236
00:13:42,400 --> 00:13:45,960
It's a very simple equation, but
the more water you put into a 

237
00:13:45,960 --> 00:13:48,360
rock, the more it melts and the 
more you can extract. 

238
00:13:48,920 --> 00:13:50,960
And of course what we're 
interested in is this 

239
00:13:50,960 --> 00:13:55,280
extraction, which is what forms 
Astorica rich, calcium rich and 

240
00:13:55,280 --> 00:13:59,360
sodium rich rocks. 
So I would say the best way to 

241
00:13:59,360 --> 00:14:03,960
make a continent is add water. 
So would it be fair to say that 

242
00:14:03,960 --> 00:14:07,920
if you didn't have the water a 
you wouldn't have the volume of 

243
00:14:07,920 --> 00:14:12,520
rocks formed that we see, and B 
they would have a different 

244
00:14:12,520 --> 00:14:17,840
composition because of the kind 
of partial melting that takes 

245
00:14:17,840 --> 00:14:19,520
place? 
Perfectly said. 

246
00:14:19,520 --> 00:14:22,480
Yes, If we didn't have water 
travelling into our crust and 

247
00:14:22,480 --> 00:14:25,720
travelling into our mantle, we 
would have a very different 

248
00:14:25,720 --> 00:14:28,120
world. 
We would probably have smaller 

249
00:14:28,120 --> 00:14:30,960
continents, as you said, because
they'd be less volume and they 

250
00:14:30,960 --> 00:14:33,920
would have a very different 
composition because the melting 

251
00:14:33,920 --> 00:14:36,760
reactions, the reactions of 
different minerals to create 

252
00:14:36,760 --> 00:14:38,200
that would be radically 
different. 

253
00:14:39,240 --> 00:14:44,840
Is the water part of the story 
as to why we don't see TCGS 

254
00:14:44,840 --> 00:14:47,760
forming later? 
That just wasn't enough water to

255
00:14:47,760 --> 00:14:52,000
form that kind of Celtic rock. 
Oh, that's a very interesting 

256
00:14:52,000 --> 00:14:55,200
question. 
So we know that water is very 

257
00:14:55,200 --> 00:14:58,840
important in making granites. 
Actually, this is only an idea 

258
00:14:58,840 --> 00:15:02,480
that's really come around in the
past 25 years or so or 30 years.

259
00:15:02,560 --> 00:15:05,080
We're understanding how 
important water in the crust is,

260
00:15:05,840 --> 00:15:09,000
and most granites, especially 
the granites which we see being 

261
00:15:09,000 --> 00:15:12,600
made today, say in volcanic 
arcs, actually do have a lot of 

262
00:15:12,600 --> 00:15:15,960
water in their source region. 
The water just comes from 

263
00:15:15,960 --> 00:15:18,160
seduction zones. 
It comes from seduction of 

264
00:15:18,160 --> 00:15:23,360
oceanic crust. 
The switch between TTGS and 

265
00:15:23,360 --> 00:15:27,840
granites is, I think, a little 
bit more messy than that. 

266
00:15:28,440 --> 00:15:31,720
I think it could be looking at a
change in thermal regime. 

267
00:15:31,920 --> 00:15:36,400
So the Archaean being hotter, it
could be a source problem. 

268
00:15:36,400 --> 00:15:40,320
So the basalts forming the TTGS 
could have a very different 

269
00:15:40,320 --> 00:15:44,600
composition to the basalts and 
ultramipic rocks which granites 

270
00:15:44,600 --> 00:15:47,240
come from. 
And it could also be plate 

271
00:15:47,240 --> 00:15:50,160
tectonics. 
You go from modern, right now we

272
00:15:50,160 --> 00:15:54,000
have this, as I said, this very 
steep cold subduction which 

273
00:15:54,000 --> 00:15:57,320
seems to release water which 
eventually creates a granite. 

274
00:15:58,040 --> 00:16:00,960
Whereas in the Archaean, perhaps
we didn't have that, perhaps we 

275
00:16:00,960 --> 00:16:04,480
had more collision or shallow 
hot subduction. 

276
00:16:04,800 --> 00:16:07,840
So there's really all these 
different things which come into

277
00:16:07,840 --> 00:16:10,000
play. 
So if you melt the bath salts 

278
00:16:10,000 --> 00:16:15,560
and you make TTGS early on, it's
a very similar process that 

279
00:16:15,560 --> 00:16:20,880
produces the granites of today, 
but they have less magnesium in 

280
00:16:20,880 --> 00:16:21,600
them. 
Is that right? 

281
00:16:22,320 --> 00:16:24,880
Yeah, it's kind of really hard 
to put the finger on this 

282
00:16:24,880 --> 00:16:28,200
because there's like 3 or 4 
different reasons why that's the

283
00:16:28,200 --> 00:16:30,760
case. 
So it's like kind of all tangled

284
00:16:30,760 --> 00:16:32,920
up. 
But yes, it's a similar process 

285
00:16:33,080 --> 00:16:35,160
to now. 
It just seems that these 

286
00:16:35,160 --> 00:16:37,480
different ingredients, the 
starting composition and the 

287
00:16:37,480 --> 00:16:41,120
processes seem to be different. 
But water seems to be the key 

288
00:16:41,120 --> 00:16:43,640
player all throughout the 
Earth's history. 

289
00:16:44,360 --> 00:16:47,160
It's just a question of how do 
you get the water to those 

290
00:16:47,160 --> 00:16:49,920
temperatures? 
What is the main difference then

291
00:16:49,960 --> 00:16:54,520
between T2 GS and modern day 
granites? 

292
00:16:54,880 --> 00:16:58,000
It simply seems to be this 
geochemical difference. 

293
00:16:58,360 --> 00:17:00,320
It could be different starting 
compositions. 

294
00:17:00,320 --> 00:17:02,720
You could explain this all by 
having different basils in the 

295
00:17:02,720 --> 00:17:06,200
Ikean verses now and therefore 
making different platonic 

296
00:17:06,200 --> 00:17:08,800
magmatic rocks. 
Or you could have different 

297
00:17:08,800 --> 00:17:11,760
temperatures of melting which 
make these different protonic 

298
00:17:11,760 --> 00:17:14,280
rocks. 
Or you could have different 

299
00:17:14,359 --> 00:17:16,720
pressures of melting which use 
lutonic drugs. 

300
00:17:16,720 --> 00:17:20,359
So this is also one of the 
reasons why our field has been 

301
00:17:20,800 --> 00:17:24,440
tangled up for so long. 
But the fundamental difference 

302
00:17:24,440 --> 00:17:27,319
is that modern day granite is 
very potassium rich, so you have

303
00:17:27,319 --> 00:17:31,600
a lot of K feldsparse, but TTGS 
it's much more sodium and 

304
00:17:31,600 --> 00:17:34,400
calcium feldsparse instead. 
Yes, exactly. 

305
00:17:34,400 --> 00:17:36,840
That is the main difference. 
Does that mean it's got more 

306
00:17:36,840 --> 00:17:40,120
plasoclase? 
Precisely, yes, much more pledgy

307
00:17:40,120 --> 00:17:42,600
glaze versus K fell spot. 
It's a very simple switch. 

308
00:17:43,000 --> 00:17:46,760
The other thing this could all 
be driven by is differences in 

309
00:17:46,760 --> 00:17:50,040
fractional crystallization. 
So I've talked a lot about the 

310
00:17:50,040 --> 00:17:52,800
partial melting processes 
because that's what I work on. 

311
00:17:53,640 --> 00:17:57,720
But of course, once you make a 
magma, you can fractionally 

312
00:17:57,720 --> 00:18:00,840
crystallize it, so you can form 
crystals which format fallout 

313
00:18:00,840 --> 00:18:04,120
fall to the bottom of the magma 
chamber or magma system, and you

314
00:18:04,120 --> 00:18:06,000
can differentiate your melt that
way. 

315
00:18:06,480 --> 00:18:09,320
So that could also be one of the
processes creating these 

316
00:18:09,320 --> 00:18:13,840
differences between modern day 
granites and Archaean TTGS. 

317
00:18:14,720 --> 00:18:16,280
There's a reason it's not solved
yet. 

318
00:18:18,960 --> 00:18:23,200
Today, about 30% of the Earth's 
surface is covered by 

319
00:18:23,200 --> 00:18:26,560
continents, as I mentioned early
on. 

320
00:18:26,560 --> 00:18:31,080
I'm wondering, do we know if 
this kind of continental volume 

321
00:18:31,080 --> 00:18:35,400
was formed in a burst early on 
in Earth history, for example 

322
00:18:35,400 --> 00:18:40,200
when the TTGS started to form? 
Or did the amount of continental

323
00:18:40,200 --> 00:18:43,200
lithosphere accumulate steadily 
over geological time? 

324
00:18:43,520 --> 00:18:46,280
It is really one of the things 
that remains the most unknown. 

325
00:18:46,800 --> 00:18:49,680
And as I mentioned, there is 
like one big problem that 

326
00:18:49,680 --> 00:18:52,240
hinders our understanding of 
this, and that's the 

327
00:18:52,240 --> 00:18:56,440
preservation bias. 
So is what we have preserved now

328
00:18:56,560 --> 00:18:59,760
on Earth, when we look back at 
our 8% of the rocks that are key

329
00:18:59,760 --> 00:19:03,200
in does it actually represent 
what was on the surface at that 

330
00:19:03,200 --> 00:19:07,040
time or does it represent one 
type of rock which was able to 

331
00:19:07,040 --> 00:19:09,640
be preserved more easily? 
Or is it chance? 

332
00:19:09,640 --> 00:19:12,560
Is it luck? 
Because we're always looking at 

333
00:19:12,560 --> 00:19:15,880
this balance between creation of
continental crust and 

334
00:19:15,880 --> 00:19:17,480
destruction of continental 
crust. 

335
00:19:17,960 --> 00:19:21,120
And those two things don't have 
to be the same throughout time. 

336
00:19:21,120 --> 00:19:24,520
They can change. 
And of course, because some of 

337
00:19:24,520 --> 00:19:28,320
this cross has been destroyed, 
it makes it very hard to say 

338
00:19:28,360 --> 00:19:31,080
something about about what we've
actually lost from the 

339
00:19:31,080 --> 00:19:37,200
geological record. 
I would say that what we see in 

340
00:19:37,200 --> 00:19:42,080
the geological record is 
impacted by a preservation bias.

341
00:19:42,080 --> 00:19:45,360
It does not represent the world 
at that time. 

342
00:19:45,560 --> 00:19:48,320
So we have to really take this 
into account when we're trying 

343
00:19:48,320 --> 00:19:52,000
to understand our crustal growth
models, as you say, which is the

344
00:19:52,000 --> 00:19:54,680
total volume of continental 
crust on the air. 

345
00:19:55,400 --> 00:19:58,440
I mentioned that you're 
interested in the possible role 

346
00:19:58,440 --> 00:20:03,400
of hydrogen in powering the 
earliest forms of life. 

347
00:20:04,040 --> 00:20:07,480
First of all, can life really be
fueled by hydrogen? 

348
00:20:07,480 --> 00:20:09,200
Are we talking about molecular 
hydrogen? 

349
00:20:09,720 --> 00:20:13,240
And presumably this was well 
before the Earth's atmosphere 

350
00:20:13,240 --> 00:20:16,080
became oxygenated. 
That's exactly right. 

351
00:20:16,080 --> 00:20:18,880
So we're talking about molecular
hydrogen or H2. 

352
00:20:19,560 --> 00:20:23,440
And yes, this is well before the
atmosphere was oxygenated. 

353
00:20:23,440 --> 00:20:28,720
So the great Oxygen Asian event 
was around 2.4 to 2.1 billion 

354
00:20:28,720 --> 00:20:32,640
years ago, but we seem to have 
had evidence of life well before

355
00:20:32,640 --> 00:20:36,080
that. 
So this is quite a fun thing 

356
00:20:36,080 --> 00:20:41,680
because these types of organisms
are called Archaea and some of 

357
00:20:41,680 --> 00:20:43,840
them are hydrogen, some of them 
is methane. 

358
00:20:43,840 --> 00:20:46,760
They use all sorts of different 
compounds to get their energy. 

359
00:20:46,920 --> 00:20:49,520
And these particular type of 
methanogens, they're called, 

360
00:20:49,520 --> 00:20:54,080
they use molecular hydrogen, H2 
and CO2 to form methane. 

361
00:20:54,160 --> 00:20:55,720
And this is their main energy 
source. 

362
00:20:56,920 --> 00:20:59,080
And incredibly, they're still 
around today. 

363
00:20:59,080 --> 00:21:01,960
So we believe that they evolved 
in the Archaean, but we can 

364
00:21:01,960 --> 00:21:04,080
still find them today. 
They're in our guts, they're in 

365
00:21:04,080 --> 00:21:07,120
our mouths, and they're living 
in the Atlantic Ocean in 

366
00:21:07,120 --> 00:21:09,880
hydrothermal vents where they 
get hydrogen from rocks. 

367
00:21:09,880 --> 00:21:13,320
So they seem to be quite 
prolific in the world. 

368
00:21:14,080 --> 00:21:17,480
So, but the key problem was in 
the Archaean for the Great 

369
00:21:17,480 --> 00:21:21,120
Oxygenation event, the 
atmosphere was really primarily 

370
00:21:21,120 --> 00:21:25,240
composed of nitrogen, carbon 
dioxide and perhaps methane or 

371
00:21:25,240 --> 00:21:27,640
ammonia. 
So this meant that the first 

372
00:21:27,640 --> 00:21:32,200
life forms had to be anaerobic. 
They couldn't use oxygen as an 

373
00:21:32,200 --> 00:21:37,640
energy source to create energy. 
So this group of Archaea, they 

374
00:21:37,920 --> 00:21:41,400
most likely evolved in the 
oceans or in shallow lakes in 

375
00:21:41,400 --> 00:21:44,400
the Archaean where they were 
using this molecular hydrogen. 

376
00:21:45,000 --> 00:21:50,400
And how would the hydrogen be 
produced in these Archaean 

377
00:21:50,640 --> 00:21:54,120
oceans or lakes? 
Yeah, it's a fantastic question 

378
00:21:54,120 --> 00:21:56,800
because we come back to these 
wonderful commodities I 

379
00:21:56,800 --> 00:21:59,560
mentioned earlier, these highly 
magnesium lavas. 

380
00:22:00,240 --> 00:22:04,800
So quite incredibly, the exact 
same reaction which tracks water

381
00:22:04,800 --> 00:22:08,600
in these rocks. 
This hydration reaction is also 

382
00:22:08,600 --> 00:22:13,680
actually an oxidizing reaction. 
So during this hydration, the 

383
00:22:13,680 --> 00:22:16,760
iron 2 plus in the rock is 
converted to iron 3 plus. 

384
00:22:17,400 --> 00:22:20,880
And because of the unique 
chemistry of these rocks, this 

385
00:22:20,880 --> 00:22:24,920
in turn dissociates the water so
it traps oxygen in the rocks and

386
00:22:24,920 --> 00:22:28,800
releases hydrogen. 
And it's quite amazing. 

387
00:22:28,800 --> 00:22:31,480
It's all kind of the same 
chemical reaction, doing all of 

388
00:22:31,480 --> 00:22:34,640
these things, hydrating the 
rock, oxidizing the rock and 

389
00:22:34,640 --> 00:22:38,720
releasing the hydrogen. 
And because we think the oceans 

390
00:22:38,720 --> 00:22:41,800
then also had quite a lot of CO2
in them, we see evidence for 

391
00:22:41,800 --> 00:22:45,040
that in the sedimentary record. 
So these Archaea would have had 

392
00:22:45,040 --> 00:22:49,160
the CO2, the hydrogen to combine
to make methane and survive. 

393
00:22:50,360 --> 00:22:53,600
And the intriguing thing is that
this could also be a possible 

394
00:22:53,600 --> 00:22:56,960
way for the evolution of life on
other planets where there's not 

395
00:22:57,080 --> 00:23:00,160
any oxygen, but there might be 
water available. 

396
00:23:00,160 --> 00:23:02,640
And also these oxidizing 
reactions taking place. 

397
00:23:03,400 --> 00:23:07,040
We can also go one step further,
which is why I kind of mentioned

398
00:23:07,040 --> 00:23:10,600
before is you brought up 
interestingly this kind of dying

399
00:23:10,600 --> 00:23:14,080
off of the commodity eye about 
2.5 to 2 billion years ago, 

400
00:23:15,000 --> 00:23:17,160
which actually directly 
correlates with the great 

401
00:23:17,160 --> 00:23:20,400
oxygenation event. 
So this big switch in how the 

402
00:23:20,400 --> 00:23:23,440
Earth, the solid Earth and also 
the atmosphere seem to work. 

403
00:23:24,480 --> 00:23:27,200
And there's been a few studies 
that have actually suggested 

404
00:23:27,440 --> 00:23:31,320
that these commodities produce 
so much hydrogen in the oceans 

405
00:23:31,520 --> 00:23:35,120
that are acted as a drawdown for
oxygen from the atmosphere to 

406
00:23:35,120 --> 00:23:39,080
recombine to make H2O water. 
And that actually the 

407
00:23:39,080 --> 00:23:41,960
commodities, the Earth cooling 
and the commodities starting to 

408
00:23:41,960 --> 00:23:44,440
be erupted less and less. 
Therefore, producing less and 

409
00:23:44,440 --> 00:23:48,000
less hydrogen actually is what 
allowed the oxygen levels in the

410
00:23:48,000 --> 00:23:51,480
atmosphere to finally take off, 
leading to the great Oxygenation

411
00:23:51,480 --> 00:23:54,040
event. 
What are you working on at the 

412
00:23:54,040 --> 00:23:56,800
moment? 
So at the moment I'm finishing 

413
00:23:56,800 --> 00:24:00,000
up my work looking at the 
interactions between commodities

414
00:24:00,000 --> 00:24:02,800
and the ocean and the atmosphere
to understand some of the 

415
00:24:02,800 --> 00:24:05,720
chemical cycling that may have 
been taking place at that time. 

416
00:24:06,480 --> 00:24:09,840
And I'm starting to look more 
towards the TTG production. 

417
00:24:09,840 --> 00:24:14,360
So creating models to try to 
understand exactly how these 

418
00:24:14,360 --> 00:24:16,960
basalts may have melted and to 
constrain what we were 

419
00:24:16,960 --> 00:24:20,360
discussing before. 
Really, what were the greatest 

420
00:24:20,360 --> 00:24:22,680
effects? 
Temperature, pressure, water 

421
00:24:22,680 --> 00:24:24,600
availability, starting 
composition? 

422
00:24:24,640 --> 00:24:28,400
How did they all play a role in 
creating the TTGS? 

423
00:24:29,240 --> 00:24:35,640
Is the existence of the TTGS 
viewed as a puzzle, or do we 

424
00:24:36,000 --> 00:24:38,760
understand enough not to be 
surprised if they're there, but 

425
00:24:38,760 --> 00:24:40,560
you're trying to flesh out the 
details? 

426
00:24:40,800 --> 00:24:42,920
I would like to flesh out the 
details. 

427
00:24:42,920 --> 00:24:45,040
The details in this point 
matter. 

428
00:24:45,560 --> 00:24:49,000
It seems like there is a non 
unique solution to creating 

429
00:24:49,000 --> 00:24:52,360
TTGSI think I mentioned before. 
And there's also a non unique 

430
00:24:52,360 --> 00:24:56,360
solution from going from these 
TTGS to the more potassium rich 

431
00:24:56,360 --> 00:24:59,360
rocks we have in the more recent
geological record. 

432
00:25:00,200 --> 00:25:03,880
So the focus of my next study is
to work out what actually are 

433
00:25:03,880 --> 00:25:08,240
the most important factors. 
And also a lot of the studies 

434
00:25:08,240 --> 00:25:11,120
have done very broad scale 
studies, but I'm hoping to go 

435
00:25:11,120 --> 00:25:14,120
more into depth looking at very 
particular case studies and some

436
00:25:14,120 --> 00:25:17,120
of these Arcan terrains to try 
to wiggle out. 

437
00:25:17,120 --> 00:25:19,480
What are the most important 
parts of this recipe? 

438
00:25:20,840 --> 00:25:22,800
Renee Tamblyn, thank you very 
much. 

439
00:25:23,080 --> 00:25:24,840
Thank you, Oliver, it's been 
very fun. 

440
00:25:24,920 --> 00:25:28,800
I enjoyed it a lot. 
To see pictures and 

441
00:25:28,800 --> 00:25:34,200
illustrations that support this 
podcast, go to geologybytes.com,

442
00:25:34,320 --> 00:25:37,080
where you'll also find a subject
matter index of all the 

443
00:25:37,080 --> 00:25:39,440
episodes. 
There you can also give me 

444
00:25:39,440 --> 00:25:43,400
feedback which I welcome, as 
well as sign up to get my emails

445
00:25:43,400 --> 00:25:44,600
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